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Water Treatment Scale Corrosion Inhibitor CAS 2809-21-4 HEDP 60%

Name:HEDP/1-Hydroxyethylidene-1,1-diphosphonic acid
CAS: 2809-21-4
Chemical formula: C2H8O7P2
Appearance: 60% clear liquid
Application:Used in detergents, water treatment, cosmetics and pharmaceuticals. Used in corrosion inhibition in circulating cool water systems, oil fields and low-pressure boilers with electric power, the chemical industry, metallurgy and fertilizers.
Availability:
Quantity:
  • HEDP 60%

  • SINOBIO

  • 3808940090

1-Hydroxy Ethylidene-1,1-Diphosphonic Acid(HEDP)




Chemical Properties


CAS Number: 2809-21-4

Molecular Formula: C₂H₈O₇P₂

325ff0b675fd4f6eef6d58c4afc2349a_HEDP

Molecular Weight: 206.02

Appearance: Colorless or pale yellow transparent liquid (60% aqueous solution), white powder (solid form)

Density: ≥1.34 g/cm³ (20°C)

pH Value: pH ≤ 2.0 in 1% aqueous solution

Solubility: Soluble in water, insoluble in organic solvents

Stability:

High-Temperature Resistance: Effective at 250°C

Acid-Alkali Resistance: Stable within pH 2-12 range

Chlorine Oxidation Resistance: Performance superior to most organic phosphates



HEDP 60% Specification:


Item  Standard 
Appearance

Clear colorless to pale tan liquid, free from foreign matter

Active Acid % 60.0 min

Phosphorous acid as PO33- %

2.0 max

Phosphoric acid as PO43 %

0.8 max
Chloride as Cl  ppm 100 max

Sequestrant value (CaCO3) mg/g as

product at PH 11-12

500 min
PH (1% solution) @20 °C 2.0 max
Density (20℃),g/cm3
1.440 min
Iron content (Fe ppm) 35.0 max
Colour (Hazen) 80 max



HEDP 60% Core Functions


1. Scale Inhibition and Corrosion Inhibition

*Chelates calcium, magnesium, iron, and other metal ions to prevent scale formation

*Dissolves metal surface oxides to inhibit corrosion

*Synergistic effect when blended with polycarboxylic acid-type scale inhibitors

2. Cleaning Agent

* Metal cleaning: Removes oxide layers from metal surfaces such as iron, copper, and zinc

* Dyeing industry: Acts as a peroxide stabilizer and color fixative

* Cyanide-free electroplating: Replaces cyanides as a chelating agent

3. Other Applications

* Pharmaceutical industry: Carrier for radioactive elements

* Electronics industry: Cleaning agent additive

* Household chemicals: Additive for household chemical products



HEDP 60% Advantage:


The core advantages of HEDP 60% (60% hydroxyethylidene diphosphonic acid solution) lie in its highly efficient scale inhibition, strong corrosion inhibition, high temperature resistance, environmental friendliness, strong compatibility, and cost-effectiveness. A detailed analysis is provided below:


1. High-efficiency scale inhibition performance

*Mechanism: HEDP 60% forms stable hexagonal ring chelates with metal ions such as calcium, magnesium, and iron in water, effectively inhibiting the formation of scale and deposits.

*Effect: It maintains high-efficiency scale inhibition even under high-temperature (below 250°C) and high-hardness water conditions, significantly reducing equipment scaling rates. For example, after a refinery adopted a formulation containing 5-10 mg/L HEDP, the scaling cycle of heat exchangers was extended from 3 months to 2 years.

*Application scenarios: Industrial circulating cooling water systems, boiler water treatment, oilfield injection water systems, etc.


2. Strong corrosion inhibition performance

*Mechanism: HEDP 60% forms a dense protective film on metal surfaces, blocking the contact of corrosive substances such as water, oxygen, and chlorine with the metal, thereby slowing down the corrosion rate.

*Effect: When used in combination with molybdate, it can significantly reduce the corrosion rate of carbon steel equipment in sulfur-containing water, extending the treatment cycle to over 2,000 hours.

*Application Scenarios: Corrosion protection for metal pipelines, heat exchangers, boilers, and other equipment.


3. High-Temperature Resistance and Wide pH Stability

*High-Temperature Stability: HEDP 60% remains active at temperatures below 250°C, making it suitable for high-temperature environments such as hot water circulation systems and boilers.

*pH Adaptability: Stable within a pH range of 2-12, outperforming traditional polyphosphates (e.g., sodium hexametaphosphate becomes ineffective due to hydrolysis at pH > 7).

*Application Scenarios: Circulating cooling water systems in the petrochemical and power industries, as well as industrial scenarios requiring acid and alkali resistance.


4. Environmental Friendliness

*Low Toxicity and Low Pollution: HEDP 60% has an LD₅₀ (oral, rat) > 2000 mg/kg, classified as a low-toxicity product; High biodegradability (some products reach 90%), resistant to hydrolysis, no phosphate emissions, reducing eutrophication pressure on water bodies.

*Compliance: Complies with EU REACH regulations (water discharge concentration must be below 1 mg/L), serving as an environmentally friendly alternative to traditional phosphate-containing water treatment agents.

*Application scenarios: Fields with strict environmental requirements, such as electronic industry cleaning and daily chemical additives.


5. Compatibility and Synergistic Effects

*Compatibility: HEDP 60% can be blended with various water treatment chemicals such as polycarboxylates, zinc salts, and defoamers to enhance overall performance. For example, when blended with polycarboxylate-based scale inhibitors, it produces a synergistic effect with a scale inhibition rate exceeding 95%.

*Application Scenarios: Complex industrial systems requiring comprehensive water treatment, such as circulating cooling water treatment in the petrochemical and power industries.


6. Cost-Effectiveness and Practicality

*Cost-Effectiveness: High purity (60% active components) and stability reduce waste and the need for reprocessing; easy to store and transport, lowering logistics and storage costs.

*Multifunctionality:

-Cleaning Agent: Adding 0.1–0.5% can soften water quality, enhance cleaning power, and avoid phosphate eutrophication issues.

- Textile industry: Acts as a peroxide stabilizer and color fixative, improving cotton fabric whiteness by over 15% and colorfastness by half to one grade.

- Electronics industry: Used for semiconductor cleaning to remove metal impurities from silicon wafer surfaces.

- Agriculture: Acts as a fertilizer enhancer, increasing phosphorus utilization by 20%-30%.

*Application Scenarios: Covers multiple fields including industry, agriculture, daily chemicals, and electronics, meeting diverse needs.



Package and Storage:


HEDP 60% : 220 kg drum or 1250 kg / IBC.

Storage for one year in shady room and dry place.


hedp 60  HEDP  HEDP

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