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Organic Peroxide Industrial Tert-Butyl Perbenzoate (TBPB) CAS 614-45-9 for Thermoplastics/Dispersion Polymers

Tert-Butyl Perbenzoate (TBPB, CAS 614-45-9) is an organic peroxide with the chemical formula C₁₁H₁₄O₃. It is primarily used as a free radical initiator in polymerization reactions and resin curing.
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Tert-Butyl Perbenzoate (TBPB) for Thermoplastics/Dispersion Polymers



Tert-Butyl Perbenzoate (TBPB, CAS 614-45-9) is an organic peroxide with the chemical formula C₁₁H₁₄O₃. It is primarily used as a free radical initiator in polymerization reactions and resin curing. It is thermally unstable and must be stored at low temperatures and protected from shocks and friction. The following are its detailed specifications:


Chemical Properties


*Molecular Formula and Structure: C₁₁H₁₄O₃, containing peroxy bonds (-O-O-), belonging to the perbenzoate class.


*Physical State: Usually a colorless or pale yellow liquid, possibly existing in solvent solutions (such as ethanol or phthalates).


*Melting Point and Boiling Point: Melting point approximately 8-9℃, boiling point around 112℃ (decomposes).


*Density: Approximately 1.034 g/cm³ (25℃).


*Solubility: Insoluble in water, readily soluble in organic solvents.


*Thermal stability: The peroxide bond is sensitive to heat; above 60°C, it may self-decompose at an accelerated rate, potentially leading to combustion or explosion. The half-life is 10 hours at 124°C.



Tert-Butyl Perbenzoate Specification


Appearance Colorless transparent liquid
UN NO 3103
CAS NO 614-45-9
Assay 99%min
Color no. : Platinum-Cobalt
≤80
TBHP%
≤0.2
Moisture %
≤0.2
Hydrolyzed chlorine %
≤0.01
Free Acid(asC6H5COOH)%
≤0.1
Reactive oxygen%
≥8.07%
Refractive index
1.495-1.505
Melting point 8
Flash point 96
SADT 63
Form Liquid
Solubility Insoluble in water
Application Used as a medium temperature initiator of polymerization reactions (such as polystyrene, polyethylene, polyacrylic acid), curing agent of unsaturated polyester resin, and vulcanizing agent of silicone rubber.




Tert-Butyl Perbenzoate Main Uses


1. Polymerization Initiator:

* In free radical polymerization (e.g., LDPE production), TBPB decomposes at 60-100℃ to generate free radicals, promoting the polymerization of monomers such as ethylene.

* Used in the manufacture of polymers such as PVC.


2. Resin Curing Agent:

* As a crosslinking agent for unsaturated polyester resins, improving the material's hardness and heat resistance.


3. Chemical Synthesis Intermediate:

* Participates in organic synthesis reactions, such as oxidation processes.



Packaging & Shipping


Standard package:  25kgs Drum.
Sample is also  avaliable, provide customized package for different quantity.


Delivery time: 7-15 working days after receiving your deposit or according to clients requirement.


Our advantages: exporting directly which obeys China Customs, with sufficient capacity, stable supply and rigid quality control.

Tert-Butyl Perbenzoate (3)   Tert-Butyl Perbenzoate (2)
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